| Sex | Athlete | DOB | Discipline | Round | POS | Mark |
|---|---|---|---|---|---|---|
| W | Lecabela Quaresma | 26/12/1989 | 60 Metres Hurdles | Pentathlon | 2 | 8.51 |
| W | Lorène Dorcas Bazolo | 04/05/1983 | 60 Metres | Heats | 6 | 7.39 |
| W | Lecabela Quaresma | 26/12/1989 | High Jump | Pentathlon | 3 | 1.76 |
| W | Cátia Azevedo | 09/03/1994 | 400 Metres | Heats | 3 | 54.17 |
| W | Lecabela Quaresma | 26/12/1989 | Shot Put | Pentathlon | 6 | 14.12 |
| W | Lecabela Quaresma | 26/12/1989 | Long Jump | Pentathlon | 10 | 6.01 |
| W | Lecabela Quaresma | 26/12/1989 | 800 Metres | Pentathlon | 9 | 2:19.85 |
| Sex | Athlete | DOB | Discipline | Round | POS | Mark |
|---|---|---|---|---|---|---|
| M | Tsanko Arnaudov | 14/03/1992 | Shot Put | Final | 12 | 19.93 |
| W | Portugal | 4x400 Metres Relay | Heats | 5 | 3:35.43 | |
| M | Nelson Évora | 20/04/1984 | Triple Jump | Final | 3 | 17.40 |